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Lemon, Christopher M. ; Maher, Andrew G. ; Anderson, Bryce L. ; Bloch, Eric D. ; Huynh, Michael ; McCollar, Abie L. ; Nocera, Daniel G. ( , Inorganic Chemistry)
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Lemon, Christopher M. ; Maher, Andrew G. ; Mazzotti, Anthony R. ; Powers, David C. ; Gonzalez, Miguel I. ; Nocera, Daniel G. ( , Chemical Communications)Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb( v ) bis-μ-oxo corrole that photochemically oxidises the C–H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-electron photoreaction.more » « less
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Solis, Brian H. ; Maher, Andrew G. ; Dogutan, Dilek K. ; Nocera, Daniel G. ; Hammes-Schiffer, Sharon ( , Proceedings of the National Academy of Sciences)